Diary of a Mad Scientist

12/31/2008

goodbye horrible year

Filed under: — girl Mark @ 12:19 pm

Really, really, really, really, really looking forward to the return of my interesting life after the New Year.

I’m getting better just in time, which is nice- I am still having some sporadic problems with breathing, pain, heartbeat issues, and fatigue, and I haven’t tried any physical work in a while, but my concentration and word-finding and other cognitive and ‘energy’ stuff is far better just in the last 10 days or so.

I can read again, which was a big issue for several months. Greg and I ordered older editions of a chemistry textbook for $4 each, and are going to wade through some of the online free MIT ‘opencourseware’ chemistry courses. I am grateful for the modern world and it’s conveniences, let me tell you.

The improvement is coming just in the nick of time (I did raise my medication dosage), just two-three weeks ago I was really starting to wonder if it was ever going to get better and starting to have serious logistical problems that required me to have real money again (like paying for the next immensely expensive round of medical testing, finding myself unable to afford my current lifesaving medication some weeks, moving my crap crosscountry finally, etc). I feel lucky that many people helped- people I know, and Greg, and people whom I don’t know at all, all came out of the woodwork and took care of enough of my needs that I didn’t flounder completely. I’m tearing up just thinking about the support I’ve received and the kindness of a couple of strangers.

I feel really lucky that I came out of this disabling state- and there was work, without my having to go looking for it. It’s exciting and interesting work, exactly what I want to be doing, I have a 2-year plan involving a proposed international project, and a 10-year plan involving something entirely unrelated, and I’m looking forward to life again.

My really exciting new research project job is starting to take shape, I’m headed to California tomorrow to deal with projects that were orphaned at the beginning of this illness in May, and everything is just fabulous. Sometime this winter I should be moving to Asheville to go work on process optimization for Blue Ridge Biofuels, exactly what I want to do for a job at the moment, I’ve got awesome research projects lined up for a couple of clients, I’ll be picking up my gas chromatograph in California, which is all set up and ready to go for ASTM 6584 (I was on the 3-year plan for that- started putting it together this time 3 years ago!),.

I just immersed myself in 48 hours of reading some industrial chemistry relevant to what I’m trying to research, and life is just plain good. About the only thing I still hope for is that with my work and project schedules, I get to be here in Pittsboro long enough to enjoy it again- I spent 4 whole months barely able to leave the house and it’s been really isolating. I’m not in a hurry to leave now that I have perfect roommates and friends in town and am actuallly mobile again.

Considering how indescribably horrible the last few months have been- in September and October I was so sick that I thought there was a distinct possibility that the disease would kill me, and the remaining months haven’t been much better- I think I am long overdue for things being fabulous.

Happy new year everyone..

12/26/2008

Good article on biofuels in today’s economy

Filed under: — girl Mark @ 12:33 pm

http://southwestfarmpress.com/energy/energy-independence-1223/

Biofuels and energy independence in uncertain times

Dec 23, 2008 8:14 AM, By David Bennett
Farm Press Editorial Staff

Thirty-five years ago this month, President Richard Nixon declared the country would be energy independent in a mere seven years. Obviously, that didn’t work out, but economist Joe Outlaw says it wasn’t a bad idea then and still isn’t.

“It’s easy for people to be cynical — ‘Energy independent? We can’t do that’ — but my point is every little bit helps as long as the economics and a business model support it,” said the co-director of the Texas-based Agricultural and Food Policy Center at the recent American Society of Farm Managers and Rural Appraisers annual meeting in San Antonio.

The “whole complex” of biofuels is “tremendous. Lots of people say I’m a biofuels apologist. What I am is a realist. I don’t care what anyone says, we’re going to have biofuels in this country. The politicians want it. For the most part, consumers want it.”

What really matters is the economics.

“At the end of the day, I’m an economist. Economics matter, but I’m not going to try and convert the rest of you. It doesn’t matter if I like ethanol or biodiesel or the people producing it. If they can’t make money doing it, they won’t be in (the business) for long.”

When the economics turn south, as they did with biodiesel recently, “people say, ‘Well, this is fine, but I’m not going to lose money on every gallon I make.’ They’ll sit back for a while and come back when the price moves back in their favor.”

Even in such an environment don’t be dissuaded, cautioned the economist. Biofuels, in some form, are here to stay.

Back to the 1980s?

Since 1960, domestically manufactured liquid fuel supply has remained relatively steady. Consumption, however, has remained on a steady track northwards. Referencing a chart showing a large gap in domestic supply and demand, Outlaw said, “Sure, this is last year’s chart and won’t show that prices got so high this year we used less, but it still shows the trend. Frankly, it tells all you need to know: we need more fuels and we probably don’t need to be so picky about where they come from.”

Many are comparing the current situation with ethanol to the early 1980s. At that time, “we had over 100 ethanol plants and then we went to 12. Well, a lot of people think we’ll go back there. I can tell you that the circumstances are completely different.”

For one thing, the United States is “more motivated to produce our own fuels for a number of reasons — 9/11 and other things. But the main difference is when (Congress passed) an RFS (Renewable Fuel Standard) that says ‘We’ll blend this much of these types of fuels.’ That’s a game-changer in this arena. It makes everything different.”

Outlaw said while he doesn’t agree with everything the Department of Energy does, he does believe when it comes to funding research “they have a good approach, saying, ‘We don’t know what technology — cellulosic production and other stuff — going forward will be the winner. So we’ll fund a whole lot of different things.’”

Food prices rise

Earlier this year, a debate raged across the country on the cause of food price increases. After releasing a study titled “The Effects of Ethanol on Texas Food and Feed,” the AFPC found itself in much demand. Outlaw was even called to speak before the Senate Energy Committee for the first time. Why? “Because we came out with some results that showed you can’t blame ethanol solely for what’s happened with food prices.”

Unfortunately, biofuel proponents and news stories then cited the report as saying ethanol was blameless. However, that isn’t what the authors stated. Ethanol was one of “many other factors that needed to be talked about.”

Among the things the report actually said were impacting food prices:

• Strong global economic growth.

• Weak dollar relative to many foreign currencies. “I don’t think anybody would tell me I’m wrong. When you had a weak dollar it made our very expensive corn very cheap and we were exporting more last year at all-time high prices then ever before. You knew the value of the dollar was encouraging that.”

• Recent crop problems (like wheat).

• Increased volume of trading in commodities by funds.

• Biofuels.

• Higher energy prices.

The timing of the report’s release coincided with the Texas governor asking for a Renewable Fuel Standard (RFS) waiver. “So, it looked like the state’s major agriculture institution was coming out against his waiver request. That isn’t right — there were things in the report that supported the waiver and things that didn’t. We tried to be balanced.”

Policies

Outlaw then showed a long list of government policies and statements regarding biofuels since the 1970s.

“Most people forget that the blender’s credit was put in place in the 1970s. It’s been around for 30 years and no one really cared that much because we didn’t produce that much. Now that we’re producing something like 9 billion gallons times 51 cents, that’s a chunk of change and people” are paying attention.

The “big thing” that pushed biofuel production was the Energy Policy Act of 2005 which installed a Renewable Fuel Standard. Even at lower levels that weren’t binding “that started the trend where we’re at now. It also didn’t hurt that (President Bush) talked about ethanol in the 2006 State of the Union.”

In 2007, with the second energy bill — the Energy Independence and Security Act — the RFS “were extended way up and talked about other types of fuel.”

The 2005 act “basically capped corn-based ethanol. It only went to 2012, but it was going to stay flat. Now, we’ll jump up to about 15 billion gallons (out of a 36 billion gallon total) by 2022 and cap it there.”

A “big chunk” of the 36 billion gallons, “will come from advanced fuels. Some will be cellulosic biofuels or biomass diesel; however you want to get there.”

No link

A surprise to some, there isn’t strong linkage between the prices of crude oil, ethanol and biodiesel. Why is that? “Because when you have a fuel like ethanol that is used by oil companies when they feel like it, when it’s in their favor to use it, it isn’t a one-for-one price link.

“What’s happened in the last year, or so, is crude oil (prices) have gone up and down and biodiesel has been all over the place. Ethanol has been relatively flat. All have been going down recently.”

Looking at contract highs for the current year, “we’re well over $7 lower on beans and wheat. Looking at the corn crop, the USDA says it won’t be much different than the one they said we’d have when the price was $8. So there’s a whole lot of speculation in this deal.”

Livestock

When the AFPC’s report on food prices came out, Outlaw’s “biggest task” was “explaining it to our livestock industry. They said, ‘Joe, we can’t pay $6.50 for corn and make any money.”

When the report was released, “we called all the commodity organizations in the state and said we’d get a room in Austin and tell them about the study so they didn’t hear about it secondhand.”

There was much agreement when “we pointed out that feed costs were killing our feeding industry — $172 per head expected losses in Texas feed yards. The cattle feeders were nodding. But when we said you couldn’t blame ethanol for all this, the same people said, and this is a quote, ‘I can’t believe that someone that’s so right about (the $172) could be so stupid about’” ethanol’s lack of blame.

“People’s emotions were running high on the issue. We did a lot of work looking at actual production costs. Everyone was blaming the farmer for these high prices, saying they were getting too much for their commodities.

“But in fact, they hadn’t even harvested those crops yet. And they couldn’t use the futures market when elevators wouldn’t give forward contracts.”

The media talked about high commodity prices, “but no one was ever able to capture those. We even had high cotton prices for a couple of weeks. No one got them because no one could afford the risk exposure on margin calls. So, we had to do a lot of explaining.”

During the report’s fallout, the only call Outlaw “really enjoyed” was from a reporter in Dallas “who asked if ethanol was driving up the bread price. I said, ‘What do you think we make bread out of?’ ‘Corn!’ ‘No, you need to fix your story. It’s actually wheat. We do have cornbread, but that’s a different thing.’”

One of the things Outlaw pointed out is while distiller’s grains are a great feed “with inclusion rates, you just can’t replace it one-for-one with corn. There are certain feeding percentages that must be used. And it’s all where the ethanol is and cattle don’t tend to be there. There’s a geographic distribution problem.”

However, the bigger issue with the distiller’s grains is the price, which was expected to remain cheap. In fact, the price followed corn. While it may have been more readily available in some areas than corn, “it wasn’t as cheap as it was made out to be.”

The future

While he admits a lack of knowledge regarding biofuel manufacturing processes, Outlaw is certain there are “really smart people who will soon crack the (cellulosic) code, whether enzymatically, using gasification or chemical processes. It will happen.”

Outlaw actually bought stock in a company claiming a process that derived fuel from wood. The claims proved overblown. “If anyone wants to give me a quarter, they can have these shares of stock I purchased. I’d be money ahead based on what they’re worth now.”

Even so, “someone will do it. But I don’t know how soon. The chemical part is only one part of the problem.”

Transportation of biomass is another part of the puzzle. Delivering 2,000 trucks of biomass to a plant daily “will make the road a little busy.” Outlaw has heard from those who seem eager to convert corn-based ethanol plants to cellulosic. Even now, “they have a lot of trucks come in — but not 2,000 trucks a day. It will be a logistical nightmare.”

And too many times people are getting ahead of the available technology.

“At a producer meeting not far from here, a producer stood up and said he was going to stop growing 3,000 acres of cotton and switch to sweet sorghum. He’d heard a guy talk about the potential of sweet sorghum and he was going to get in on the ground floor. But he hadn’t been told it wasn’t ready yet — there’s no market, no seed.”

Outlaw was the one “to break the news that (the producer) wasn’t going to be the first rich guy in the county. I’ll do that but I don’t like it much.”

Portfolio of opportunities

In Outlaw’s opinion, “we’ll have a portfolio of opportunities going forward. I can’t tell you who’s got the answer. But it’s annoying when someone comes up and says, ‘This is what we’re going to do, this is the way it’s going to be, and it’s going to work and you’ve got tell everyone.’ That’s annoying because, at the end of the day, no one (yet) knows” how it will shake out.

“People shouldn’t have their feelings hurt if the (energy source) they’ve put their money in, or the one they think should happen, isn’t the one that turns out to be the long-term winner.”

During his testimony before the Senate Energy Committee, the most valuable question asked of Outlaw was, “So we get cellulosic ethanol. What happens to corn-based ethanol?”

“I said, ‘Well, Senator, assuming the government doesn’t change a lot of the things you do, it’s all going to be driven by economics: the cost of production of corn-based versus the cost of production of these other things. If they’re very close, we’ll have both. If one is a lot higher than the other, we won’t have it. That’s just the way the market works. That doesn’t mean I like it but that’s the way the world works.’”

email: dbennett@farmpress.com

12/23/2008

Next Steps

Filed under: — girl Mark @ 1:15 pm

Well I’m deeply excited about what’s next. In some ways, i’m right back where I left off back in August when I got too sick to function, but oh well, nothing I can do about it now. it’s a few lost months, and hopefully I won’t lose any more to this dreadful disease. I still don’t know for sure what I had (because I haven’t been able to afford testing), but it responds to babesia/malaria therapy, and presumably babesiosis infection or something else transmitted by a tick bite at the beginning of the summer.

I have to spend a few weeks in California, unfortunately-I’m not quite ready to really travel for that long, and I’ve gotten really thrashed by traveling for the last few jobs that I’ve done and classes that I have taught. But, it’s down to the wire on several things I have been putting off for seven months as a result of this illness, mainly the fact that I have to go back to California and finish moving. I’ve been paying rent on the studio/shop space for a year, not too much money back when I was working, but certainly a bad idea the moment. At some point, I’m going to have to load all that crap onto trailer and drive it cross country, but for the moment, I just go there for three weeks and get it out of the shop. I tried to put off that trip as long as I could.

On the other hand, I’m really, really excited about seeing friends while on the trip, and I’m even more excited about this being the beginning of a new phase. Again, I was supposed to start that new phase months ago - especially a dream job I got in August that I’m now just picking up again- but let me tell you, there’s nothing quite like being dysfunctional for months to make you really appreciate health, energy, and being able to do things.

I’m doing a research proposal dance with several consulting clients at the moment, and should be delving back into high-FFA oil research/esterification research this winter. On the trip to California, I am also picking up my GC, and shipping it back here. I can’t wait. I’ve been a little bit stuck here for lack of a good space to do wintertime R&D in- there’s nothing for rent around here that I can afford, and my shop space here is an unheated tractor shed. I’m having some funny ideas about picking up an old camper trailer-middle of winter, in the middle of a recession, should be a really good time to find a small camper for $500-and turning it into a small lab space and office. We’ll see what happens.

12/21/2008

Food versus fuel links- might be wingnutty

Filed under: — girl Mark @ 9:46 am

I’m cautiously posting a link to an Infopop biodiesel forum discussion on ethanol and food versus fuel- most of the time these threads devolve into libertarians versus liberals, both spouting ideology rather than real information, but so far, this one is a good compendium of links and articles about the issue:
http://biodiesel.infopop.cc/eve/forums/a/tpc/f/429605551/m/5471091742?r=8491051382

12/11/2008

Classes, Classes, Classes- all over the land

Filed under: — girl Mark @ 2:28 pm

Biodiesel Production Hands-on Classes:

-Beginners: Hands-on Crash Course: Operate Your Own Reactor format
-Advanced Topics: Hands-on Advanced Topics course on ethanol biodiesel, methanol recovery, high-FFA oils, and more

with Maria ‘girl Mark’ Alovert
and guest instructors (Advanced Topics)

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Biodiesel Production Crash Course class schedule:

Marietta, OH
Jan 17-18

Oxford, MS
Feb 21-22

Fayetteville, TN
Feb 28-Mar 1

Mifflinburg, PA
March 12-13

Edmund, OK
Mar 26-27

Bartlett, NH
April 4-5

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Biodiesel Advanced Topics/Farm Scale biodiesel production class schedule:

Mifflinburg, PA (with Preston Boop of Briar Patch Organic Farms)
March 14-15

Edmund, OK (with Carl Shortt of Okiebiofuel.com)
March 28-29

upcoming: Anchorage, Alaska Crash Course and Advanced topics classes, early June
possible Seattle WA Advanced Topics class, late May

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cost:
$140 regular and $108/$95 early registration (see website for cutoff dates for early registration discounts)

no one turned away for lack of funds

For more information and to register, please see www.girlmark.com/tour
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Biodiesel Production Crash Course:

This is a fast-paced class designed to quickly teach the skills needed for safely making high quality biodiesel, using a unique and truly hands-on format. Students will ‘learn by doing’ by making their own 5-gallon batches of biodiesel from beginning to end. There is also an opportunity to build your own full-size reactor to take home for those who purchase a parts kit in advance.

Students will spend one day learning basic theory, practicing titration, making mini-batches, and learning quality testing. The second day is devoted to solidifying the theory you just learned, by making biodiesel in realistic “Processor Stations’, practicing every step used in a full-size home biodiesel production system. Student teams will operate realistic, tabletop 5-gallon processor systems- a miniature version of the common Appleseed Processor/wash tank/dry tank found around the world- and the tabletop reactor will familiarize them with every valve, tank, pump, switch, and interconnect that would be found in a full-size system. The goal of the class format is to take the hands-on learning experience a big step beyond the ‘1-liter mini-batch’ equipment used in most biodiesel classes. There will also be a full-size reactor system on a trailer at the class, including GL-1 and pot still-type methanol recovery systems.

Background for Crash Course class:

In most biodiesel workshops (including my own Biodiesel Essentials), “hands-on time” usually means a few hours of lab work involving titration and shaking 1-liter soda bottle batches, or, at best, a demonstration by the instructor of some pre-arranged steps in a full-size reactor, performed once, with the students just watching. Neither of these is an ideal learning method for the complexity involved in using a ‘real’ biodiesel reactor on your own for the first time at home. People who are hands-on learners sometimes need more time on “realistic” equipment operation in addition to the 1-liter shaken soda bottle batch method.

Operating your own processors in class would be more realistic than 1-liter glassware batches. Operating a full system can also make it easier to understand equipment choices that face you as you design your own home system after the class, or help decide on one to purchase.

Format:
In the crash course, you will first learn the basic theory using a standard one-day mini-batch class, then spend the next day actually operating (with a team of 5-8) your own ‘realistic’ 5-gallon mini-reactor and processing system. You and your team will make decisions and mistakes, with constant personalized guidance to ensure that you understand why every step is done as well as when.

Equipment Building (Crash Course class):
We can also build some processors at the end of the Crash Course, for those students who wish to purchase a parts kit and water heater tank in advance. This is not mandatory and everyone can help build the systems.

Preparation and reading:

Because this is a fast-paced class, it is highly recommended that you purchase, ahead of time, an inexpensive mini-titration/test batch kit from www.utahbiodieselsupply.com and try to make and wash a soda-bottle test batch, using storebought, new oil, before the class. This is not mandatory but the preparation will enhance your class experience.

To make the class run smoothly and so that you get the most out of it, please read the www.biodieselcommunity.org website before the class, so that you have some idea of the basic process. Copies of Biodiesel Homebrew Guide will also be available for sale fpr $15 at the class: www.localb100.com/book.html , and there will be a short handout with some basic formulas for later reference.

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Advanced Topics Biodiesel Production Hands-on Class:
The advanced class is designed for those who already make biodiesel (full-scale or test batches) or have attended hands-on workshops by teachers such as Jennifer Radtke, John Bush, Steve Fugate, BioLyle Rudensey, Carl Shortt, Piedmont Biofuels, Matt Steiman, Frankie Lind, Kalib Kersch, or others who teach from the http://biodieselcommunity.org techniques (check with me if a class is your only hands-on experience).

I encourage experienced biodiesel producers to bring a presentation or photos of their system and discuss their experiences.

This class is geared to both homebrewers and fleet/farm/small commercial producers.

The class covers a wide range of topics, geared especially towards larger scale ‘home’ production. The class specifically offers heavy hands-on focus on making biodiesel with several major techniques that are useful in your “skillset":

working with high-free-fatty-acid oil

working with high-water feedstocks

acidulating glycerine and wash water for easier disposal and cost savings

testing biodiesel, glycerine, and wash water for soap

producing biodiesel from oils recovered from glycerine

acid-catalyzed esterification options

methanol recovery from biodiesel (GL-1 process) and glycerine.

using glycerine as a solvent in various stages of the process

There will be an extensive hands-on section of the class devoted to techniques for making biodiesel using ethanol instead of methanol, and we will discuss small-scale fuel ethanol production.

We will also discuss water-free soap removal such as the use of the GL-1 process and ion exchange resins.

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About the instructor:
Maria ‘girl Mark’ Alovert is a biodiesel production technology consultant based in North Carolina. She is the author of The Biodiesel Homebrew Guide, a manual on biodiesel production (http://localb100.com), the founder of the community-written biodiesel homebrewing tutorial site http://biodieselcommunity.org and is the inventor of the Appleseed Processor, an ‘open source’ design now used by thousands of people around the world to produce biodiesel on a ‘homebrew’ scale. She has been involved in home-scale biodiesel technology development since 2000, and is currently researching production techniques for high-FFA oils/acid-catalyzed esterification, and ethanol-based biodiesel. She frequently teaches beginning and advanced biodiesel production classes around the country and is a an active participant in biodiesel production discussion forums such as http://biodiesel.infopop.cc

For more information and to register, please see www.girlmark.com/tour

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